ACM Awards 2016: 15 Best and Worst Moments

From breakout performances to busted jokes

Best Harmonies: Cassadee Pope and Chris Young
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Best Harmonies: Cassadee Pope and Chris Young

While there were several notable cross-genre collaborations throughout the night, one of the best match-ups from a pure vocals standpoint came with the pairing of Chris Young and Cassadee Pope on their hit single, "Think of You." The former Voice victor and the classically trained Young matched each other note for note on the chugging, broken-hearted power ballad, their voices intertwining with hand-in-glove precision. The stage rained sparks at the end of the song but all the firepower necessary was already evident.

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