13. David Addison and Maddie Hayes, 'Moonlighting'
With sexual chemistry so combustible it's a surprise TV screens didn’t explode, Bruce Willis and Cybil Shepherd took the Sam & Diane dynamic of Cheers to the next level in a 1980s comedy that gave both actors one of their most memorable turns in the spotlight. Inspired by The Taming of the Shrew, the screwball private-eye show helped launch Willis into superstardom and revived Shepherd's career years after The Last Picture Show kickstarted it. Watch this odd couple interact and their subsequent success is no secret.