50 Best 'Mad Men' Characters

From one-off cameos to Sterling-Cooper's core players, we're ranking the show's most memorable characters

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Dr. Faye Miller
50
Michael Yarish/AMC15/50

15. Dr. Faye Miller

Showcase Episode: "The Beautiful Girls"
Yet another inspired Sopranos casting touch — Carla Buono was Christopher's wife Kelli before playing Dr. Faye Miller, the steamy psychiatrist who analyzes the fuck out of Don. She totally has his number: "You only like the beginnings of things." And oh yeah, she has a dad in the mob — "He's a handsome two-bit gangster like you."

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