Tim McGraw and Faith Hill
Faith Hill was engaged to her producer Scott Hendricks when she launched a tour with Tim McGraw in 1996. Unfortunately for Hendricks, the two country superstars fell in love and Hill called off the engagement. Hill and McGraw married later that year, and they remain country's ultimate power couple. Their 2006 co-headlining tour made more money than any tour in the history of country music. In recent years, Hill has devoted much of her time to raising the couple's children.