Written by Zac Brown and his bandmate, Wyatt Durette, "As She's Walking Away" was inspired by a woman in a bar. "We had just played a show in Orlando," Durette recalls. "Zac and I went to a bar in Orlando to watch a UFC fight...It was just one of those circumstances where you see a pretty girl in a bar and you don't have the guts to walk over and say hello to her." Alan Jackson contributed vocals, which undoubtedly helped the tune soar to the top of the charts. The song won the band a Grammy for Best Country Collaboration With Vocals.