Click here to listen to Pearl Jam's two-disc 'Pearl Jam Twenty'

One of the most stunning moments in Cameron Crowe's new Pearl Jam documentary comes near the end, when the band plays "Better Man" at Madison Square Garden and the audience euphorically screams along to every word. The soundtrack to the film – which contains that "Better Man" – is for those hardcore fans. There's no "Jeremy," "Daughter" or "Even Flow" here. But there is a gorgeous demo of "Nothing as It Seems" from 1999, a demo of the 1990 Temple of the Dog track "Say Hello 2 Heaven" and an early version of "Alive," from Pearl Jam's second show, in December 1990. The emotional high point may be "Crown of Thorns," from a gig in 2000. The song was first cut by Mother Love Bone shortly before their frontman Andrew Wood died; the group recruited Vedder and changed its name to Pearl Jam. Wood always dreamed that his band would be hugely famous, and in Vedder's hands his greatest song is reborn as the arena-rock anthem it was meant to be.

Related:
• Cameron Crowe on 'Pearl Jam Twenty': 'We Went About as Personal as We Could Get'
• 'Pearl Jam Twenty' Documentary Unearths Rare Footage, Artifacts from Band's Past
• Readers Poll: The Best Pearl Jam Songs of All Time
• Video: First Trailer for 'Pearl Jam Twenty'
• Pearl Jam in Posters: A Gallery of Illustrated Tour Art

“Youth Knows No Pain”

“Like on 'Youth Knows No Pain' — we are the ones that should demonstrate, because we can take it,” Likke Li said. “We can pierce ourselves, take Ecstasy, dance all night and still go to work at our McDonald's jobs.” Despite the hedonistic sentiment in the song, the Swedish singer also admitted in hindsight her youth had repercussions. “I remember when I was 18-19 and feeling that I know it all,” Li said. “I always feel that I know it all. But that song is about realizing you don’t, and reflecting, ‘Boy, if I only knew what would follow.’”