'From Russia With Love' (1963)
The second Bond film is also the most raw of the series. It's far closer to the character Ian Fleming created in his novels than the gadget-fixated mannequin of the later films with Pierce Brosnan. Connery takes on the evil SPECTRE, foils former KGB agent Rosa Kleb (the great Lotte Lenya gets her kicks as a killer lesbian with a poisonous blade in the tip of her shoe), and still has time to make time with a hottie Soviet defector (Daniela Bianchi). Director Terence Young tops himself with a punchfest on the Orient Express between Bond and Red Grant (a bottle-blonde Robert Shaw) which is one of the great fight scenes in any movie. Connery ranks the film as his favorite. Ironically, so does his latest successor, Daniel Craig.